9 bbn structure

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This colourless solid is used in organic chemistry as a hydroboration reagent. The compound exists as a hydride-bridged dimer, which easily cleaves in the presence of reducible substrates. The compound is commercially available as a solution in tetrahydrofuran and as a solid. Its highly regioselective addition on alkenes allows the preparation of terminal alcohols by subsequent oxidative cleavage with H 2 O 2 in aqueous KOH. The steric demand of 9-BBN greatly suppresses the formation of the 2-substituted isomer compared to the use of borane. Contents move to sidebar hide. Article Talk.

9 bbn structure

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EC Number. ISBN

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B -alkylBBN preparation is itself a two-step process, thus restricting the utility of the 9-BBN for synthetic purposes. These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves. This is a preview of subscription content, log in via an institution. Unable to display preview. Download preview PDF. Article Google Scholar.

9 bbn structure

This colourless solid is used in organic chemistry as a hydroboration reagent. The compound exists as a hydride-bridged dimer, which easily cleaves in the presence of reducible substrates. The compound is commercially available as a solution in tetrahydrofuran and as a solid. Its highly regioselective addition on alkenes allows the preparation of terminal alcohols by subsequent oxidative cleavage with H 2 O 2 in aqueous KOH. The steric demand of 9-BBN greatly suppresses the formation of the 2-substituted isomer compared to the use of borane.

Hugo sarrazin

Tools Tools. The steric demand of 9-BBN greatly suppresses the formation of the 2-substituted isomer compared to the use of borane. The following other wikis use this file: Usage on de. Chemical formula. Main page Welcome Community portal Village pump Help center. Organic Syntheses. SVG development InfoField. Solubility in water. Description 9-BBN structure. The source code of this SVG is invalid due to 13 errors. Nature America, Inc.

Ramos uclm. The commercial 9-borabicyclo[3.

EC Number. The substitution of any brackets is due to technical restrictions. Organic Syntheses via Boranes. Retrieved 18 June In other projects. Captions Captions English Add a one-line explanation of what this file represents. Other names Borabicyclononane Banana borane. The correct title of this article is 9-Borabicyclo[3. Infobox references. Article Talk. Summary [ edit ] Description 9-BBN structure. Wikimedia Commons. You cannot overwrite this file. Read Edit View history. The following other wikis use this file: Usage on de.